Alumina-chrome refractory
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Manigault, Edward L.; |
An improved alumina-chrome refractory composition having increased strength at both ambient and high temperatures has been prepared comprising the following ingredients: PRETEXTREPLACED
BACKGROUND OF THE INVENTION
An alumina-chrome refractory brick composition has been prepared by the prior art which contains the following composition:
Tabular Alumina 70-96%
Calcined Alumina -325 mesh
0-10%
Milled Zircon -325 mesh 1-10%
Chromic Oxide Refractory Grains
Ground to -10 mesh with at Least
70% +200 mesh 3-10%
Bentonite 0-4%
Water 0-10%
Phosphate Compound 0-18%
Such a product has been useful as refractory brick composition for use in the ferrous and non-ferrous industries. Although this prior art refractory product possesses high strength, it is desirable to produce a refractory composition which has a higher modulus of rupture at both ambient and high temperatures.
SUMMARY OF THE INVENTION
It has been discovered that the refractory composition of the prior art refractory product comprised of alumina and pigment grade chromic oxide (-325 mesh) may be improved considerably by employing chromic oxide refractory grains which are present in the fused or sintered form. This fused or sintered chromic oxide refractory grains should be ground to -10 mesh with at least 70`% +200 mesh, as opposed to the prior art method which employs pigment grade chromic oxide 70is 100% -325 mesh size.
The refractory composition produced by the instant invention comprises the following:
Tabular Alumina 65-90%
Calcined Alumina 0-10%
Chromic Oxide (-325 mesh)
1-25%
The mixture is then formed and fired at 350.degree. to 1750.degree.C. for 2 to 8 hours if desired.
If phosphates are not employed then the firing temperature should fall within the range from 1400.degree. to 1750.degree.C.
If a ramming or plastic mixture is to be produced, the mixture itself is used directly without forming and firing for the customers use. In the case of preparing a plastic mixture, from 1% to 4% bentonite is also added to the mixture.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
In preparing the refractory composition of the instant invention it is important to have present in the mixture a variety of sizes of the various ingredients employed. Tabular alumina may be used as the only source of alumina, but it is preferred to have a mixture of tabular and calcined alumina.
The tabular alumina should be employed in various sizes. All of the -1/4 inch +325 mesh alumina should be employed in the tabular form and in addition, with respect to the -325 mesh alumina, from 1/4 to all of the -325 mesh alumina should be present in the tabular form. If calcined alumina is used, it should be -325 mesh in size. 65% to 95% of the alumina should be -1/4 inch to +325 mesh in size, while the remainder of the alumina should be ground to -325 mesh.
The chromic oxide refractory grains should be ground to -10 mesh in size with at least 70% +200 mesh, and should be obtained from either previously fused or sintered chromic oxide.
It is preferred that zircon be employed in amounts from 1% to 10%, preferably from 3% to 7%. The size of the zircon should be -325 mesh.
In preparing the refractory composition of the instant invention, the alumina raw material, the ground refractory grains of chromic oxide, and the milled zircon are mixed together, and are formed into shapes which are then fired to form the desired refractory product. The mixture is fired at temperatures from 350.degree.C. to 1750.degree.C. for 2 to 8 hours to form the refractory composition. When phosphates are not employed the mixture should be fired at temperatures from 1400.degree.C. to 1750.degree.C.
The refractory composition of the instant invention possesses increased modules of rupture at both ambient and high temperatures. Although an increased modulus of rupture at ambient temperature is desirable, it is more preferable to have an increased modulus of rupture at high temperatures such as that mentioned above.
In order to describe the instant invention more fully, the following examples are presented:
EXAMPLE 1
The following ingredients were added to form a refractory mixture:
Tabular Alumina 70-95%
Calcined Alumina 0-10%
Milled Zircon 1-10%
Chromic Oxide Refractory Grains
Ground to -10 mesh 3-10%
with at Least 70% +200 mesh
Bentonite 0-4%
Water 0-10%
Phosphate Compound 0-18%
The mixture was then tempered with lignin liquor and formed into bricks 9 in. .times. 41/2 in. .times. 3 in. and the bricks were then fired at 1560.degree.C. for 5 hours. After cooling to room temperature, the bricks were analyzed to determine their strengths which are listed as follows:
Tabular Alumina -8+65 mesh, Kg.
44
Tabular Alumina -65+325 mesh, Kg.
22
Tabular Alumina -325 mesh, Kg.
19
Calcined Alumina -325 mesh, Kg.
5
Chromic Oxide Refractory
Grains -10 mesh with at Least 70%
+200 mesh Kg 7
Zircon -325 mesh, Kg.
3
EXAMPLES 2-3
The procedure of Example 1 was repeated except that various amounts of zircon were added to the mixture in Examples 2 and 3. Bricks having properties similar to those obtained in Example 1 were produced.
The operational details and the results obtained are recorded in Table I along with those of Example 1.
For comparison, a series of control runs were made with various compositions.
CONTROLS A-C
In these runs no chromic oxide was employed. Run A contained no zircon. Runs B and C contained zircon.
The results of these runs indicateed that modulus of rupture at both ambient temperature and at 1480.degree.C. were unsatisfactory.
The results are recorded in Table II.
CONTROLS D-F
In these runs pigment grade chromic oxide was employed instead of coarse chromic oxide refractory grains and the results were inferior to those obtained in Examples 1-6.
The results are also recorded in Table II.
It has been discovered that the use of coarse chromic oxide refractory grains increases the bond strength at higher temperature over that retained when finely divided chromic oxide is employed.
EXAMPLES 4-5
In these examples aluminum phosphate was used in Example 4 while phosphoric acid was employed in Example 5. The results are also recorded in Table I.
It should be noted that the modulus of rupture results at both ambient and 1480.degree.C. temperatures were high and in addition the porosities were reduced and the bulk densities were increased over those produced in Examples 1-3.
The phosphates when employed are added to develop a ceramic body which possesses high strength at reduced temperatures i.e. above 350.degree.C. Phosphates are also added to reduce the porosity and increase the bulk density which results in reduced penetration when the ceramic body is in contact with molten metals on slags.
While this invention has been described and illustrated by the examples shown it is not intended to be strictly limited thereto, and other variations and modifications may be employed within the scope of the following claims.
Modulus of Rupture
Ambient Temp. High Temp. (1480.degree.C.)
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8777 5122
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